Gravimetric Determination of Phosphorus in Fertilizer Samples Essay

I. AbstractThe target of this try aside is to determinethe Phophorus inwardness of plant food trys victimisation Gravimetric analytic thinking. It involves dissolution of the plant food prove, foolhardiness and heating and cooling of the stress. Pooled standard deviations of the 2 data sets for % Pwet, %Pdry, %P2O5 wet and %P2O5 dry were 5.1448, 5.1472, 11.8436 and 11.8504 respectvely. During the test a data rejection for %P and %P2O5 was cerebrate at approximately 20% and 47%. Determination of the morning star content in fertilizer is vital in timbre assurance and in the choosing of a fertilizer grade chief(prenominal) for agriculture.II. Introduction launchs bring essential nutrients such as Nitrogen, Phosphorus, kelvin or Sulfur to grow. However, most soils lack these macronutrients olibanum a decrease in food overlapion. In connection with this, the mathematical function of fertilizers check intoing these macronutrients has been part of the agricultural tradition. fertilisers have in its labels a set of numbers, know as the fertilizer grade that alship canal be in the form N-P-K, indicates the proportions of essential nutrients founder (ie 10-10-10 which means 10% Nitrogen, 10% orthophosphate in the form of P2O5, 10% kilobyte in the form of K2O).Different organizations widely distributed like Association of American Plant pabulum Control Officials (AAPFCO) in the coupled produces, conduct different tests to assess the accuracy and consistency of the nutrient content with regards to that of the intersection point label and also to tick tint assurance as part of consumer rights. Analysis of fertilizer can be conducted development Gravimetric Analysis.In Gravimetric Analysis, the produce with known composition is resulted from the conversion of the analyte to a dissolvable come that can be easily gain vigored and is free from impurities by subjecting it to heat. This product of known composition entrust past be wei ghed and the character of the analyte in the try can be primed(p). In this try out, the analyte, Phosphorus in the fertilizer will be go downd as Magnesium Ammonium phosphate Hexahydrate, MgNH4PO4 ( 6H2O5H2O + HPO42- + NH4+ + Mg2+ + OH- ( MgNH4PO4 ( 6H2O (s) (1)The purpose of this experiment is to determine the percentage of Phosphorus (P) and Didaystar (P2O5) in the fertilizer strain by the means of Gravimetric Analysis.III. information and ResultsIn this experiment, the wet (as received) and dry weights of the fertilizer exemplification, com forefronted from the previous experiment of moisture tendency of the same fertilizer sample were utilise. Weights were divided up into two data sets, Data spate 1 having four (4) trials and Data descend 2 having three (3) trials.The desiccated sample from the previous experiment from which moisture was determined, was fade out and is converted into a sparingly alcohol-soluble precipitate, MgNH4PO4 ( 6H2O which is and then st rained and weighed. The trickle idea occasiond was weighed to easily determine the weight of the precipitate. The precipitate was then dried and weighed.IV. DiscussionThis experiment aims to determine the percentage of P and P2O5 in fertilizer sample using Gravimetry. The fertilizer sample from the previous experiment of wet Determination was utilized in this experiment. The dried fertilizer sample was dissolved with 40 mL di so fared water system and was then filtered to obtain a clear filtrate.In Gravimetry, it is important to use a effect broker that if not specific, should be selective and would crock up out a precipitate containing the analyte. This set up promoter should also give out a precipitate that is easily filtered and rinse from impurities, unreactive with the elements contribute in the atmosphere, of clinical depression solubility to lessen the loss of analyte during filt proportionalityn and race, and with known composition after drying or heating. In thi s compositors case, 45 mL of 10% MgSO4 ( 7H2O was added to the filtrate, with cl mL 2M NH3 as the precipitating broker to obtain the sought after precipitate MgNH4PO4 ( 6H2O which contains the analyte P. jaw Equation 1. While other precipitating agent like NH4Cl can be use, NH3 was employ otherwise to discipline that the desired precipitate would be form. The presence of Cl- ions will much likely to attract Mg2+ thence producing MgCl2 precipitates, which do not contain the analyte in this experiment which is P.It should be noted that NH3 is added soft with continuous aspiration to the solution to ensure the growth of the precipitate, resulting to a precipitate that is easier to filter and be freed of impurities. This technique is related to the von Weirmans ratio wherein the element size of a precipitate is inversely proportional to the value of carnal knowledge Superaturation given byRelative Supersaturation = picWhereQ= concentration of reactants before fallS= solub ility of the precipitatePrecipitates ar both formed by nucleation, or by blood cell growth. In nucleation, particles join unitedly to form a colossal mass, unremarkably a result of supersaturation in solutions. It consists of ample amount of precipitate, however, is composed of humiliated particles that are hard to filter. In this experiment, what is desired is particle growth that presents a precipitate of large size but of smaller number. This is executable by further precipitation wherein particles split to the surface of ab initio nucleated particles. The supersaturation acres of the solution is eased during unremitting stirring upon rundown of the precipitating agent, on that pointof promoting particle growth rather nucleation. With respect to the von Weirmans ratio, the in high spiritser the value of the ratio, the higher the accident of getting smaller particles, thereby promoting nucleation, st throw to a low-toneder value of the ratio which promotes par ticle growth that will yield larger precipitates that is important in this experiment. afterward the addition of the precipitating agent with constant stirring, the mix was allowed to stand at inhabit temperature for 15 mins. It is important to let the premix stand, without every agitation or outer forces acting on it to let digestion to occur. Digestion is requirement to allow reprecipitation, wherein particles will adhere to the initially small precipitates, and to expel water molecules thus lessening the surface area acquirable for adsorption which causes impurities to obtain larger particles with great purity and easier filterability.After 15 mins, the medley was filtered using the preweighed filter news report. The filter paper that was preweighed was kept in the dessicator until further use to keep the moisture from adhering to the filter paper. Preweighing the filter paper was helpful for easy finish of the weigth of the precipitate. During filtration, precipitate was washed with di slakeed water in small portions of 5mL twice. For each washing, the distilled water was poured into the beaker where precipitation occured to accumulate the remaining precipitates that adhered to the sides of the beaker.After washing with distilled water, two 10mL portions of 95% ethanol were used for second washing. The use of 95% ethanol, becaue of its excitability thus will dry the precipitate fast(a)er, will ensure that no more than water is trapped in the pores between the precipitates, minimal solubility loss and particles of small size will not rally up and pass through the pores of the filter paper. Smaller portions of the wash liquid were used to ensure that the precipitate will still be intact and nosignificant loss in the amount of the precipitate due to the enough of washes liquid.The filter paper containing the precipitate was then heated inside the oven set a t 110C for 1 hour and was cooled in a dessicator for 15 min. After this, the weight of t he precipitate was determined by subtracting the value of the preweighed filter paper with the weight of the filter paper including the precipitate.even though Gravimetry is considered as mavin of the efficient and less expensive ways of determining a fertilizer component, this technique is still not fool produce and errors due to classic and indeterminate detailors may lead to an erroneous result. One of these errors is the fast addition of the precipitating agent and low impact of agitation that leads to the production of larger amount of small particles that may pass through the filter paper thus having lesser amount of precipitate, and a glare value for the P or P2O5 content in the sample. On the other hand, since time the mixture stands in room temperature without any coverings, contaminants like dust particles may be included in the mixture, contributing weight to the precipitate, giving a higher yield. This high yield will give a P or P2O5 content of the sample higher than its actual value.It can be observed from Table 3 that the range of % P and % P2O5 lies between approximately 6% to 13% and 15% to 30% separately with 20% and 47% suspicious value since it is almost double of the determine in range. By performing the Q test, the set were substantiate to be accpetable with regards to the actual value and determine in the population, or jilted. Table 4.1 and 4.2 shows the set that were rejected and accepted for each data set. Notice that the 20% and 47% for % P and % P2O5 respectively, both belonging to Data suffice 1 were rejected with 95% assumption level, meaning that the Qexp exceeded the value of the Qtabulated.Of all the trials in both Data Set 1 and 2, the group with values similar to that of the rejected values were the ones who obtained the greatest amount of precipitate. put on Table 2. This rejection or errounous error in the data can be attributed to the determinate and indeterminate errors in the experiment. One more error t hat could be the reason for this rejection is the in the flesh(predicate) error in terms of the culture of the analytical balance. Also, because of this rejection in data, aside from the fact that Data Set 2 has disappoint number of population, Data Set 2 parameters for Measure of Precision are side by side(predicate) to each other, with the dried samples having greater values than that of the wet sample. Iti s because dried sample are purer than that of the wet sample containing still moisture and other interfering agent to getting the actual % P and % P2O5.V. drumhead and ConclusionsIn this experiment, it was determined that the fertilizer sample has % P range of 6% to 13% with % P2O5 from 15% to 30%. However, the usual images of fertilizers with phosphates contain a minimum of 42.5 % water soluble phosphate and 46% total phosphate by weight, as in the case of Triple Superphosphate or 85 % water soluble and 20% available in Superphosphate. It should be noted that the theoret ical values will vary depending on the type of fertilizer used in the experiment. notwithstanding the data rejection that occurred, overall, it can be say that the experiment is a success since the objectives of the experiment such as performing hydrometric analysis in the determination of phosphorus content and to know the principle in separation by precipitation were achieved.Yet, it is recommended that there would be a specific appearance of putting the precipitating agent, like addition dropwise or certain amounts per second or stirring so as to ensure the proper formation of crystals needed by the experiment. It should also be observed that upon digestion, or letting the mixture stand without agitation, the mixture should be covered to avoid impurities present in the atmosphere.VI. ReferencesChapter 3 Gravimetry. California State University, Dominguez Hills. http//www.csudh.edu/oliver/che230/textbook/ch03.htm Accessed 17 January 2013.Fischer, R.B. and Peters, D.G. Quantitati ve chemic Analysis 3rd ed. 1968 pp42-4349Food and Agriculture Organization of the United Nations. AGP Fertilizer Specifications. http//www.fao.org/agriculture/crops/core-themes/theme/spi/plantnutrition/fertspecs/en/. Accessed 04 January 2013.Rehm, G. et al. misgiving Phosphorus Fertilizers Phophorus in the Agricultural Environment. University of atomic number 25 Extension. 2010. http//www.extension.umn.edu/distribution/cropsystems/dc6288.html Accessed 17 January 2013.Skoog, D. et al. Fundamentals of uninflected Chemistry 6th ed. Saunder College Publishing. 1992 pp72-80